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**About this book :- **
**Molecular Quantum Mechanics (4th Edition) ** written by
** Peter Atkins, Ronald Friedman**.
One major change since the third edition has been our response to concerns about the mathematical complexity of the material. We have not sacrificed the mathematical rigour of the previous edition but we have tried in numerous ways to make the mathematics more accessible. We have introduced short commentaries into the text to remind the reader of the mathematical fundamentals useful in derivations. We have included more worked examples to provide the reader with further opportunities to see formulae in action. We have added new problems for each chapter. We have expanded the discussion on numerous occasions within the body of the text to provide further clarification for or insight into mathematical results. We have set aside Proofs and Illustrations (brief examples) from the main body of the text so that readers may find key results more readily. Where the depth of presentation started to seem too great in our judgement, we have sent material to the back of the chapter in the form of an Appendix or to the back of the book as a Further information section. Numerous equations are tabbed with www to signify that on the Website to accompany the text [www.oup.com/uk/ booksites/chemistry/] there are opportunities to explore the equations by substituting numerical values for variables.

(Peter Atkins and Ronald Friedman)

**Book Detail :- **
** Title: ** Molecular Quantum Mechanics
** Edition: ** 4th
** Author(s): ** Peter Atkins, Ronald Friedman
** Publisher: ** Oxford University Press
** Series: **
** Year: ** 2005
** Pages: ** 588
** Type: ** PDF
** Language: ** English
** ISBN: ** 0-19-927498-3
** Country: ** UK

**About Author :- **
The author ** Peter William Atkins ** (born 10 August 1940) is an English chemist and a Fellow of Lincoln College at the University of Oxford. He is a prolific writer of popular chemistry textbooks, including Physical Chemistry, Inorganic Chemistry, and Molecular Quantum Mechanics. Atkins is also the author of a number of science books for the general public, including Atkins' Molecules and Galileo's Finger: The Ten Great Ideas of Science, Four Laws that Drive the Universe, Reactions: The Private Life of Atoms, and What is Chemistry?

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**Book Contents :- **
**Molecular Quantum Mechanics (4th Edition) ** written by
** Peter Atkins, Ronald Friedman**
cover the following topics.

Introduction and orientation

1. The foundations of quantum mechanics

Operators in quantum mechanics

The postulates of quantum mechanics

The specification and evolution of states

Matrices in quantum mechanics

The plausibility of the Schro¨ dinger equation

2. Linear motion and the harmonic oscillator

The characteristics of acceptable wavefunctions

Some general remarks on the Schro¨ dinger equation

Translational motion

Penetration into and through barriers

Particle in a box

The harmonic oscillator

Translation revisited: The scattering matrix

3. Rotational motion and the hydrogen atom

Particle on a ring

Particle on a sphere

Motion in a Coulombic field

4. Angular momentum

The angular momentum operators

The definition of the states

The angular momenta of composite systems

5. Group theory

The symmetries of objects

The calculus of symmetry

Reduced representations

The symmetry properties of functions

The full rotation group

6. Techniques of approximation

Time-independent perturbation theory

Variation theory

Time-dependent perturbation theory

7. Atomic spectra and atomic structure

The spectrum of atomic hydrogen

The structure of helium

Many-electron atoms

Atoms in external fields

8. An introduction to molecular structure

The Born–Oppenheimer approximation

Molecular orbital theory

Molecular orbital theory of polyatomic molecules

The band theory of solids

9. The calculation of electronic structure

The Hartree–Fock self-consistent field method

calculations

Electron correlation

Density functional theory

Gradient methods and molecular properties

Semiempirical methods

Molecular mechanics

10. Molecular rotations and vibrations

Spectroscopic transitions

Molecular rotation

The vibrations of diatomic molecules

The vibrations of polyatomic molecules

11. Molecular electronic transitions

The states of diatomic molecules

Vibronic transitions

The electronic spectra of polyatomic molecules

The fate of excited species

12. The electric properties of molecules

The response to electric fields

Bulk electrical properties

Optical activity

13. The magnetic properties of molecules

The descriptions of magnetic fields

Magnetic perturbations

Magnetic resonance parameters

14. Scattering theory

The formulation of scattering events

Partial-wave stationary scattering states

Multichannel scattering

The Green’s function

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